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Chemical Management in Production Activities




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As one of the action items regarding chemical substances used in production activities, the Hitachi Cable Group targets and takes the initiative to reduce emissions of VOC substances from domestic production sites by 33% in FY2011 when compared with that of FY2001. The Group also continues to grasp and monitor the handling, released and transferred amounts of all the chemical substances purchased and maintains a database to promptly respond to new domestic and international chemical substance regulations and a framework to prevent leakage and other environmental pollution by comprehending variations of use by substance, reducing the risks posed by the use of chemical substances.

 

Chemicals emission control

 

The total amount of chemicals handled in FY2009 was 5,344 tons subject to the PRTR Law, with 91 tons of emitted chemicals and 151 tons of displaced chemicals. Though the amount handled increased when compared with that of the previous year, the amount emitted decreased. This is thanks to a reduced handling of toluene, xylene and other VOCs whose amount of emissions was large, though the handling amount of phthalic acids whose emissions were small increased.

 
 

Released and transferred amount of chemicals subject to the PRTR Law in FY2009

 
(Unit: t)
Substance number Designated chemical substance name Emission amount Displaced amount
Air Water Sewage Waste
9 Adipic acid bis
(2-ethylhexl)
0.0 0.0 0.0 7.2
25 Antimony and its compounds 0.0 0.0 0.0 4.2
29 4,4'-isopropylidenediphenol
[bisphenol A]
0.0 0.0 0.0 0.0
30 Condensation polymer of 4,4'-isopropylidenediphenol and 1-chloro-2,3-epoxypropane [bisphenol A epoxy resin] 0.0 0.0 0.0 33.5
32 2-imidazolidinethione 0.0 0.0 0.0 0.3
40 Ethylbenzene 9.1 0.0 0.0 6.9
43 Ethylene glycol 0.2 2.0 0.0 0.6
63 Xylene 24.5 0.0 0.0 14.4
64 Silver and its soluble compounds 0.0 0.0 0.0 0.0
67 Cresol 1.4 1.2 0.0 0.0 5.0
108 Non-organic cyanide compound (excluding complex salt and cyanate) 0.0 0.0 0.0 0.0
115 N- N-Cyclohexyl-2- benzothiazolesulfenamide 0.0 0.0 0.0 0.2
120 3,3'-Dichloro-4,4'- diaminodiphenylmethane 0.0 0.0 0.0 0.4
172 N,N-dimethylformamide 5.6 0.0 0.0 27.7
181 Thio uric acid 0.0 0.0 0.0 2.9
202 Tetrahydromethylphthalic anhydride 0.0 0.0 0.0 0.0
204 Tetramethylthiuram disulfide 0.0 0.0 0.0 0.1
207 Copper soluble acid (excluding complex salt) 0.0 0.0 0.0 1.3
224 1,3,5-trimethyl benzene 0.7 0.0 0.0 0.1
227 Toluene 46.2 0.0 0.0 3.3
230 Lead and its compounds 0.0 0.0 0.0 1.9
231 Nickel 0.0 0.0 0.0 0.3
232 Nickel compounds 0.0 0.0 0.0 0.4
252 Arsenic and its non-organic compounds 0.0 0.0 0.0 4.7
266 Phenol 1.6 0.0 0.0 16.6
269 Phthalic Acid Di-n-octyl 0.0 0.0 0.0 0.9
270 Phthalic Acid Di-n-butyl 0.0 0.0 0.0 0.0
272 Phthalic acid bis (2-ethyl hexl) 0.0 0.0 0.0 11.1
283 Hydrogen fluoride and its soluble salt 0.0 0.0 0.5 3.1
304 Boron and its compounds 0.0 0.0 0.1 0.7
312 Phthalic anhydride 0.0 0.0 0.0 0.0
Other 63 substances 0.3 0.0 0.0 2.7
Total 89.4 2.0 0.6 150.1
*Chemicals whose names are given are those chemicals whose handling amount is 1 ton or more (0.5 ton or more for first-class designated chemicals.)
*Figures dropping the second decimal digit are indicated so the total figure is different.
 
 
 

Reducing VOC air emissions

In relation to VOC emissions in the air, that are assumed to be a cause of photochemical oxidants and suspended particulate matters, the Hitachi Group picks up 41 substances and takes the initiative to reduce VOC emissions of these 41 VOC substances by 33% in FY2010 when compared with that of FY2001.
The number of VOC substances dealt with in FY2008 was 18, and VOC air emissions with a handling amount of 1 ton per year or more was 514 tons, and we were able to reduce VOC air emissions by the significant amount of 29% compared with FY2001. The main reason for this was that the adsorption collector of n-decane contained in copper surface cleaning agents started operations, reducing the amount of emissions. A decrease in production also contributed to the reduction of emissions. For other VOC with a large amount of emissions, isopropyl alcohol used for copper surface reduction treatment, we are now working on technical studies to reduce the amount of emissions by transferring the work to another manufacturing facility, which is expected to drastically reduce the amount of usage.

 
 
 

Reducing VOC by adsorption collector

 
 
Adsorption collector

The Tsuchiura Works uses cleaning fluid for the finish cleaning of copper products requiring a high level of surface cleanness. The cleaning fluid contains a VOC, n-decane, a large amount of which is emitted into the atmosphere during the drying process, accounting for more than 40% of total emissions by the Hitachi Cable Group, which poses a challenge to the reduction of emissions. As a countermeasure, we have installed equipment to adsorb volatilized n-decane to active carbon fibers for collection and recycling, reducing emissions by 60%. Furthermore, the collection and reuse contributed to consumption and purchase amounts of cleaning fluid, reducing costs.

 
 

Storage status of electric equipment using PCB

The processing of rendering harmless electric equipment using PCB stored in individual works will start in FY2010 at the Hokkaido Facility of the Japan Environmental Safety Corporation. A first priority is given to safety in carrying-out and transportation of equipment, and we continue to strictly store and manage equipment before carrying-out small devices not subject to immediate processing.

 
 
Site Transformer Capacitor Others (fluorescent lamp stabilizers, etc.)
Densen Works, Hitachi Cable, Ltd. 0 15 Stabilizer: 391 pieces, waste oil: 54 liters
Hitaka Works 0 46 Stabilizer: 32 pieces Fluorescent capacitors: 2,327 pieces, cotton waste: 13 cans + 2 bags
Toyoura Works 0 64 Stabilizer: 21 pieces Fluorescent capacitors: 655 pieces, cotton waste: 5 packs, waste oil: 50kg
Tsuchiura Works 1 365 Stabilizer: 573 pieces, waste oil: 4 cans, cotton waste: 3 cans
Equipment Factory, Hitachi Cable MEC-Tech, Ltd. 0 0 Stabilizer: 185 pieces
Kisai Factory, Hitachi Alloy, Ltd. 0 135 Stabilizer: 24 pieces
Ishioka Works, Tonichi Kyosan Cable, Ltd. 0 6 0

*1Storage amount as of March 31, 2009.
*2In addition to those shown on the table, there are 17 capacitors in use.
*3In addition to those shown on the table, there are 32 transformers of which 11 are in use.
*4There are 9 other capacitors in storage in combinations of minute amounts of PCB.
 
 
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